环境空气中的气溶胶污染的影响分析     

常凤池 《矿产与地质》2005,19(6):728-729,731

环境空气中气溶胶粒子是由极性气体凝聚而成,呈三峰型分布.对其空气中溶胶粒子,特别是可吸入粒子的成分,气溶胶态、粒径大小、浓度等对人体健康危害进行了分析研究.  相似文献   

北京地区春末-秋初气溶胶理化特性的观测研究   总被引：10，自引：0，他引：10       下载免费PDF全文

许黎  冈田菊夫  张鹏  张代洲  石广玉 《大气科学》2002,26(3):401-411

分析了1997年5～9月和1998年4～9月北京整层大气气溶胶光学厚度、近地面气溶胶粒子数浓度的日变化、季节变化及其与气象要素的关系,还分析了 1997年5月16日、7月21日和8月2日收集的北京单个气溶胶粒子样品的形态、大小和化学元素组成.结果显示,北京地区春末-秋初整层大气气溶胶光学厚度在0.1～1.6之间变化;气溶胶数浓度(D>0.3μm)为几～几百个/cm3;整层大气气溶胶光学厚度的日变化型式与近地面气溶胶数浓度呈现相反的走向;气溶胶光学厚度和数浓度的日、季节变化显示了整层大气和近地面大气气溶胶与该地区气象、气候条件的关系.气溶胶数浓度与大气相对湿度呈正相关,与风向的关系是偏东风数浓度大,西、西南风数浓度小.电子显微镜分析的结果表明:颗粒物的形态以不规则形、丸形、液态滴形和方形为主;颗粒物化学元素组成有Si、K、S、Al、Mg、Ca、Fe等元素;人类活动排放的Zn、P、Ti、pb、Ba等元素也探测到;北京近地面粒子的一个显著特点是富含Ca和K元素,它们可能分别来自建筑粉尘和有机物的燃烧;给出了一个典型的碳黑粒子和一个粒子经过凝结过程的"卫星"滴环绕的矿物粒子的照片和元素谱图.  相似文献   

鼎湖山自然保护区大气气溶胶中的PAHs   总被引：6，自引：2，他引：6  

祁士华  叶兆贤等 《地球科学》2001,26(1):83-87

多环芳烃（PAHs)是环境中分布广泛、危害人类健康的有机化合物，通过对鼎湖山自然保护区自然地理和大气气溶胶中苯并（a)芘分析认为，春季样品中大气气溶胶中PAHs主要来源于高等植物排放，夏季来源于珠江三角洲经济区化石燃烧排放。  相似文献   

VARIABILITY OF AEROSOL OPTICAL PROPERTIES OVER HEFEI DURING SEPTEMBER 1993 TO SEPTEMBER 1994   总被引：7，自引：0，他引：7       下载免费PDF全文

Zhou Jun  Wang Zhi''en  Han Jiecai  Hu Huanling  Li Guojie 《Acta Meteorologica Sinica》1996,10(1):81-95

An 8-wavelength sun-photometer has been operated at Hefei (31.31°N, 117.17°E) to monitoroptical properties of atmospheric aerosols. Altogether 133 solar spectral extinction data were ob-tained on clear days during the period from September 1993 through September 1994, In this pa-per, the feature of the sun-photometer is briefly described. A relative aureole method is intro-duced. which can be used to monitor temporal evolution of aerosol loading during the sun-pho-tometer calibration period. Temporal variabilities of spectral aerosol optical depths and Angstromturbidity parameters are presented. Relation of these variabilities with synoptic and local meteoro-logical conditions are analyzed and discussed, From measured spectral aerosol optical depths undersome representative atmospheric conditions, columnar aerosol size distributions have been retrievedby a linearly constrained inversion method. These typical columnar aerosol size distributions are al-so presented and discussed.  相似文献   

考虑湿度影响的城市气溶胶夜晚温度效应   总被引：10，自引：0，他引：10  

李子华  涂晓萍 《大气科学》1996,20(3):359-366

本文利用一维非定常模式，研究了城市上空干、湿气溶胶粒子对夜间边界层温度的影响。结果表明，湿气溶胶粒子对低层大气有明显的升温作用，而对中上层大气则起降温作用，同时改变了贴地逆温层结构和边界层稳定度。  相似文献   

大气臭氧与气溶胶垂直分布的高空气球探测   总被引：17，自引：2，他引：17  

石广玉  许黎  郭建东  张豹武  孙宝来  龚知本  周军  谭锟  岩坂泰信  林政彦  长谷正博 《大气科学》1996,20(4):401-407

本文给出了1993年9月12日利用高空科学气球在河北省香河地区探测到的大气臭氧和气溶胶的垂直分布。结果发现:(1) 大气臭氧的数密度在整个对流层较低(～10[12]mol/cm3)，并从地面到对流层顶略有下降；对流层顶以上开始快速增加，极值层高度在～24 km，其值为4.78×10[12]mol/cm3；臭氧分压有类似的分布特征，极值146×10[-4]Pa，位于同一高度；(2) 在平流层低层，臭氧分压有一个次极值62×10[-4]Pa，位于15～16 km；(3) 0～30 km大气气溶胶数密度呈现出三个峰值:143，8和1.1 个/cm[3]，分别位于近地面、5 km和21 km；（4）气溶胶的数密度谱在对流层为双模态；在平流层，次峰消失。同时，我们还与其他观测结果作了比较分析。  相似文献   

火山气溶胶的辐射影响   总被引：2，自引：1，他引：2  

汪宏七  赵高祥 《大气科学》1992,16(6):755-760

本文应用辐射传输计算研究了火山气溶胶,特别是大的火山爆发后短时期及火山周围地区内的火山气溶胶,对到达地面的向下的总的太阳辐射通量、行星反照率及大气加热率的可能影响.  相似文献   

温度对平流层气溶胶光学常数及辐射特性的影响     

张建云  张国栋  许丽生 《成都信息工程学院学报》1993,(4)

本文阐述平流层气溶胶的光学常数在不同温度下取值时,用Mie散射理论对不同浓度的平流层气溶胶红外波段的辐射特性进行的计算和分析。分析结果表明:在卫星遥感中,由温度引起的平流层气溶胶光学常数的变化对某些红外波段的平流层气溶胶辐射特性的影响是不容忽视的。  相似文献   

SEM-EDX Characterisation of Tropospheric Aerosols in the Negev Desert (Israel)     

Sophie Sobanska  Cécile Coeur  Willy Maenhaut  Freddy Adams 《Journal of Atmospheric Chemistry》2003,44(3):299-322

Individual aerosol particles collected in the Negev desert in Israel during a summer and winter campaign in 1996–1997 were analysed by scanning electron microscopy with energy-dispersive X-ray analysis. Hierarchical cluster analysis was performed to interpret the data on the basis of particle diameter and composition. Eleven particle classes (groups) provided clues on sources and/or particle formation. The summer samples were enriched in sulphates and mineral dusts; the winter samples contained more sea salts, aged sea salts, and industrial particles. The fine size fraction below 1 m diameter was enriched in secondary particles and showed evidence of atmospheric processing. The secondary sulphate particles were mainly attributed to long-range transport. A regional conversion from calcite to calcium sulphate occurred during summer. Industrial particles originating from local pollution appeared during winter.  相似文献   

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene     

Richard Winterhalter  Peter Neeb  Dirk Grossmann  Antje Kolloff  Osamu Horie  Geert Moortgat 《Journal of Atmospheric Chemistry》2000,35(2):165-197

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.  相似文献